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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D217-24
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D217-24
filingDate 1969-06-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1972-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1262515-A
titleOfInvention Novel styryl isocyanates and isocarbostyriles and process for production of isocarbostyriles
abstract 1,262,515. Preparation of isocarbostyrils and intermediate isocyanates. UNION CARBIDE CORP. 24 June, 1969 [5 July, 1968], No. 31769/69. Heading C2C. Isocarbostyrils, e.g. of the general formula wherein each R<SP>1</SP> individually can be hydrogen, alkyl, alkoxy, halo, two R<SP>1</SP> variables joined together to form a ring, provided that at least one R<SP>1</SP> represents hydrogen in a position ortho to the -CR<SP>2</SP>-CR<SP>3</SP>-NCO moiety, and wherein R<SP>2</SP> and R<SP>3</SP> individually represent hydrogen, alkyl, are produced by heating at elevated temperature, e.g. 200‹ to 300‹ C., a styryl isocyanate, e.g. of the general formula The isocyanates may be prepared by known steps from the corresponding aldehyde through cinnamic acid, corresponding acid chloride, cinnamoyl azide which is heated to give the corresponding isocyanate. In an example, 3-methoxy cinnamoyl chloride obtained by reacting the corresponding acid and thionyl chloride is reacted with sodium azide to produce 3-methoxy cinnamoyl azide which is heated to produce 3-methoxy styryl isocyanate and the latter refluxed to produce 6-methoxy isocarbostyril. Many other examples are given.
priorityDate 1968-07-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 29.