http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1256203-A
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_24aca9ded2638ea793d05360dde7a4a0 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10S204-90 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10S204-912 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07B55-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C61-37 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C61-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-43 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C51-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C61-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07B- http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C- http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C61-04 |
filingDate | 1970-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1971-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1256203-A |
titleOfInvention | Racemization of optically active transcyclopropane-mono-carboxylic acids and their derivatives |
abstract | 1,256,203. Racemic - trans - cyclopropanemonocarboxylic acids. SUMITOMO CHEMICAL CO. Ltd. 20 March, 1970 [24 March, 1969], No. 13527/70. Heading C2C. Racemic trans - cyclopropane - monocarboxylic acids are obtained by irradiating the optically active acids or their derivatives with U.V. rays in the presence of a photo-sensitizer. The optically active trans-cyclopropane-monocarboxylic acids are preferably dissolved in a solvent which is transparent to U.V. rays. Such solvents include saturated hydrocarbons, saturated ethers, benzene, alkylated benzenes, alcohols, water and mixtures thereof. Compounds containing an α-oxophenyl group are useful as photo-sensitizers. A small amount of ()- cis - cyclopropane - monocarboxylic acid may be formed in the resulting product, which may be converted to the ()-trans-cyclopropane-monocarboxylic acid by conventional methods. Examples are given for the preparation of racemic trans-chrysanthemumic and transethano-chrysanthemumic acids. |
priorityDate | 1969-03-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 24.