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filingDate 1969-02-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1971-11-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1254584-A
titleOfInvention Anaerobic adhesive composition for sheets and coatings
abstract 1,254,584. Anaerobic adhesives; thermoplastic compositions. LOCTITE CORP. 25 Feb., 1969 [29 Feb.. 1968], No. 9922/69. Heading C3P. Adhesive thermoplastic compositions, which are non-flowable at 75‹ F., comprise a thermoplastic polymer plasticized with a liquid anaerobic adhesive system, the latter comprising a mixture of an acrylate or α-substituted acrylate ester and a peroxy polymerization initiator. The compositions can be in the form of a sheet or a coating material, and are suitably prepared by dissolving the polymer, ester and initiator in a volatile solvent and then evaporating the solvent from the solution formed. The ester may be an acrylate, methacrylate, ethacrylate or chloroacrylate and is preferably one that contains two or more (substituted) acrylate groups per molecule, e.g. polyethylene glycol dimethacrylate, hexamethylene dimethacrylate, dipropylene glycol dimethacrylate, diglycerol diacrylate, diglycerol trimethacrylate, neopentyl glycol diacrylate, tetra-ethylene glycol di - (chloroacrylate) or trimethylolpropane triacrylate. Monoesters such as hydroxyethyl methacrylate or t-butylaminoethyl methacrylate are also suitable. The peroxy initiator is preferably a hydroperoxide; also useful are hydrogen peroxide and peroxides and peresters which hydrolyse or decompose to form hydroperoxides. The compositions may also include quinone or polyhydric phenol stabilizers, tertiary amine or imide accelerators, additional plasticizers, thickeners and colouring agents. Suitable thermoplastic polymers include polyalkyi acrylates and polyalkyl (α-substituted acrylates), cellulose esters, butadiene-styrene copolymers, acrylonitrile - butadiene - styrene copolymers, polyvinyl chloride, vinyl or vinylidene chloride-vinyl acetate copolymers, cellulose ethers, polyvinyl acetate, polyvinyl acetals, polyesters, polyurethanes, polystyrene, coumarone-indene resins, phenoxy resins and various resins prepared from hydrophilic modified olefins.
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