http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1252903-A
Outgoing Links
Predicate | Object |
---|---|
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C309-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C311-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C309-80 |
filingDate | 1968-05-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1971-11-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1252903-A |
abstract | 1,252,903. Halosulphonylalkyl nitriles. IMPERIAL CHEMICAL INDUSTRIES Ltd. 8 April, 1969 [10 May, 1968], No. 22324/68. Heading C2C. Novel compounds I: wherein X signifies F, Cl or Br and R<SP>1</SP> and R<SP>2</SP> signify H or straight chain C 1-6 alkyl, are obtained by reacting a compound II (obtained by treating an appropriate bromo- or chloroalkane nitrile with sodium sulphite): with a mixture of phosphorus oxychloride and phosphorus pentachloride to afford compounds I wherein X is Cl or with phosphorus pentabromide to afford compounds I wherein X is Br; compounds I wherein X is F may be obtained from the corresponding chloro.compounds utilizing an alkali metal fluoride. 2,4-Dichloroaniline is reacted with 2-chlorosulphonyl-acetonitrile to afford 2,4-dichlorophenylsulphamoyl-acetonitrile; 2-(2,4-dibromophenylsulphamoyl)-valeronitrile is similarly obtained. Isobutylamine reacts with compounds I to afford the following products: and Phenylsulphamoyl-acetonitrile, obtained by the interaction of aniline and 2-chlorosulphonylacetonitrile, reacts with 2,4-dichloro-benzenediazonium chloride to yield 2,4-dichlorophenylhydrazono-acetonitrile. |
priorityDate | 1968-05-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 36.