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filingDate 1968-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_50bf2573d87ec93fd2060f88ec3b2b30
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publicationDate 1970-09-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1204430-A
titleOfInvention PROCESS FOR THE PURIFICATION OF CRUDE BIS-(beta-HYDROXYETHYL)TEREPHTHALATE
abstract 1,204,430. Purification of bis-hydroxyethylterephthalate. TEIJIN Ltd. 5 Dec., 1968, No. 57896/68. Heading C2C. A process for the purification of crude bis-(2- hydroxyethyl)-terephthalate (BHET) comprises the steps of (a) dissolving crude BHET, with heating, in an aromatic solvent, e.g. benzene, toluene, xylene, chlorobenzene, dichlorobenzene, which is liquid at room temperature, (b) cooling the heated solution to precipitate the BHET and (c) separating the precipitated BHET, wherein in the step (a) the solution contains crude BHET uniformly distributed therein, at a concentration higher than the saturation solubility of crude BHET in the solvent at the temperature corresponding to the apparent melting-point, defined below, of the crude BHET in the same solvent, at an elevated temperature above the apparent melting point; and in step (b), cooling from the elevated temperature of the solution to a temperature below the apparent melting point rapidly, so as to avoid the precipitation of granular or lumpy solid BHET; said apparent melting point being defined as the temperature at which a mixture of 1 part by weight of BHET and 5 parts by weight of said solvent become molten when heated in a sealed tube.
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