http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1187671-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0c8514878053ed09557f9014c1602409 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D333-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D333-54 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C323-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-68 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D333-54 |
filingDate | 1967-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6dc144727548c24529817f9d55b16b67 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6da734dabbb7b4d18cdd7abb5aba2e68 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d58f2d8ebf5cb6ee6738ee1ab486cdff |
publicationDate | 1970-04-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1187671-A |
titleOfInvention | Fluorinated Benzothiophen Derivatives |
abstract | 1,187,671. 4,5,6,7-Tetrafluorobenzo (b) thiophen and derivatives thereof. IMPERIAL SMELTING CORP. (N.S.C.) Ltd. 27 Feb., 1968 [26 Jan., 1967], No. 3973/67. Heading C2C. The invention comprises compounds of the general formula wherein both the groups Y are identical and Y is -COOR, -COOH or -H, and R is a hydrocarbon group, and the monohydrate of the compound wherein Y is -COOH. The compounds wherein R is -COOR are prepared by reacting a compound of the formula with a diester of acetylene dicarboxylic acid at an initial temperature below 0‹ C. Hydrolysis of the esters with 50% H 2 SO 4 gives the compound in which Y is -COOH, which compound is isolated as its monohydrate. Decarboxylation of this monohydrate using copper powder in quinoline gives the compound in which Y is H. Pentafluorothiophenol is prepared by treating pentafluorobenzene with n-butyl-lithium and adding flowers of sulphur to the resulting mixture. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103058988-B http://rdf.ncbi.nlm.nih.gov/pubchem/patent/CN-103058988-A |
priorityDate | 1967-01-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 36.