http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1175264-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_c72d118f5664072de841f9c5c34b9d99 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G77-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G64-186 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G77-448 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G77-42 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G77-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G64-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G77-448 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G77-42 |
filingDate | 1966-12-22-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_497f5c83e60ed245a99857df11136ecc |
publicationDate | 1969-12-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1175264-A |
titleOfInvention | Organopolysiloxane-Polycarbonate Block Copolymers |
abstract | 1,175,264. Organopolysiloxane - polycarbonate block copolymers. GENERAL ELECTRIC CO. 22 Dec., 1966 [3 Jan., 1966], No. 57587/66. Heading C3T. Organopolysiloxane - polycarbonate block copolymers have unsaturated terminal groups V<SP>1</SP>-OCOO- or V<SP>1</SP>-NHCOO- and comprise 1-95 wt. per cent of (A) polysiloxane blocks of units R<SP>1</SP> 2 SiO and correspondingly 5-99 wt. per cent of (B) blocks of the reaction product of a compound HO-Z-OH with a carbonyl halide or diaryl carbonate, the blocks (A) and (B) being linked by groups -R<SP>11</SP>-COO-, -R<SP>11</SP>-NHCOO-, -R<SP>11</SP>-OCONH-R<SP>11</SP>- NHCOO- or -COO-, in which R<SP>11</SP> or the C atom is linked to Si, or by -O- or -OCOO- joining a silicon atom to a group Z; wherein V<SP>1</SP> is an olefinic or acetylenic optionally halogenated aliphatic or cycloaliphatic monovalent hydrocarbon radical. In examples, a chlorine-terminated polydimethylsiloxane is reacted with an excess of bisphenol A, in Example 6 after an initial reaction with diphenylol sulphone, then with phosgene; the end groups derive from allyl alcohol (allyl phenol in Example 3) added partly before, partly after the phosgenation, or allyl isocyanate (Example 1) added after; the products contain 61-64% polysiloxane, curing to elastomers, or 15% polysiloxane (Example 5) curing rigid. The products of Examples 2 and 3 are reacted with methyldiacetoxysilane in toluene i.p.o. a Pt catalyst to give a solution which cures in moist air, after addition of stannous octoate or dibutyltin dilaurate catalyst; the product of Example 4 is milled with fume silica and dicumyl peroxide and cured to a rubber. |
priorityDate | 1966-01-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 44.