http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1175240-A

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filingDate 1967-12-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1969-12-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1175240-A
titleOfInvention Process and Device for the Manufacture of Acetoacetic Acid Esters.
abstract 1,175,240. Acetoacetic acid esters. FARBWERKE HOECHST A.G. 21 Dec., 1967 [24 Dec., 1966], No. 58147/67. Heading C2C. Acetoacetic acid esters are prepared by reacting diketene with an aliphatic or cycloaliphatic alcohol that has a boiling point below 140‹ C., in the presence of, as catalyst, a basic compound and/or a betaine and under superatmospheric pressure. Examples of the basic catalyst include tertiary amines of the formula NR 3 in which each R stands for the same or different aliphatic, cycloaliphatic, araliphatic, aromatic or alkanol radicals; cyclic tertiary amines, quaternary ammonium salts, tertiary phosphines, di- and tri-basic sodium phosphates and other inorganic salts that have alkaline reactions in aqueous solution. A preferred apparatus for carrying out the process of the invention comprises a subdivided reactor in which the reaction mixture is boiled under reflux.
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priorityDate 1966-12-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 24.