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filingDate 1968-03-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1969-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1164752-A
titleOfInvention Process for the Production of Nitroaryl Sulphonic Acids
abstract 1,164,752. Nitroaryl sulphonic acids. J. R. GEIGY A.-G. 8 March, 1968 [9 March, 1967], No. 11486/68. Heading C2C. A nitroaryl sulphonic acid is prepared by reacting a nitroaryl compound and sulphur trioxide in a ratio of 1 to 1À10 moles of sulphur trioxide per mole of nitroaryl compound by reacting in a first step at a temperature not exceeding 100‹ C. two-thirds of the nitroaryl compound with the sulphur trioxide to form the corresponding sulphonic acid anhydride and sulphonic acid monohydrate, and reacting the resultant mixture in a second step at a temperature above 100‹ C. with the remaining third of the nitroaryl compound. The process is preferably carried out in a solvent, particularly liquid sulphur dioxide. Examples are given of the preparation of (a) p-nitrotoluene sulphonic acid and 4-nitro-3-chlorobenzene sulphonic acid.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4922008-A
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type http://data.epo.org/linked-data/def/patent/Publication

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Total number of triples: 22.