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filingDate 1966-10-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_267c2b5264b9143bc4c8f38013068a6f
publicationDate 1969-08-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1162557-A
titleOfInvention Halogenation of Olefins
abstract 1,162,557. Dibromoalkanes. EL PASO PRODUCTS CO. 14 Oct., 1966, No. 46094/66. Heading C2C. Dibromoalkanes are obtained by introducing anhydrous diolefin and a molar excess of anhydrous hydrogen bromide into a reactor maintained under an anhydrous atmosphere at from - 20‹ to 40‹ C. in the absence of moisture and in the presence of a free-radical initiator. It is preferred to utilize terminal or alpha, omega-diolefins such as 1,3-butadiene, 1,4- pentadiene, 1,5 - hexadiene or 1,6 - heptadiene and the example specifies the hydrobromination of 1,5-hexadiene wherein 1,6-dibromohexane is the main product while 2,5-, 1,4- and 1,5-dibromohexane and 5- and 6-bromohexene-1 are all formed in minor amounts. However any diolefin may be used in the hydrobromination. The free-radical initiator is usually oxygen.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-6980959-B1
priorityDate 1966-10-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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