http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1113530-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_0efa077d881a96aeb1e29b21ef1bbb58 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09B23-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D209-46 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C09B57-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D209-50 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08K5-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08K5-3432 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D209-50 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08K5-3432 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08K5-34 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09K11-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09B57-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D209-46 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C09B23-04 |
filingDate | 1965-09-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9a5a6933f0b75676543021978653f1e3 |
publicationDate | 1968-05-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1113530-A |
titleOfInvention | Production of 3-substituted phthalimidines |
abstract | 3-Substituted phthalimidines having the general formulae <FORM:1113530/C4-C5/1> <FORM:1113530/C4-C5/2> wherein the groups X-C-Y and H-C-Y denote radical of a compound having an activated methylene or methyl group respectively, X and Y denote radicals with groups which are electrophilic under the reaction conditions and radicals X and Y may form a ring, and the benzene ring A may be substituted, e.g. by halogen, nitro, alkyl or aryl groups, are obtained by converting phthalodinitrile or a derivative thereof into 3-iminophthalimidine hydrochloride in aqueous alcoholic hydrochloric acid, e.g. at temperatures up to 60 DEG C. and condensing this product with a compound X-CH2-Y or Y-CH3, e.g. methyl cyanoacetate, ethyl cyanoacetate, 2-picoline, 4-picoline, quinaldine, 2,6 - dimethylquinoline, 5,6-benzoquinaldine, 1-phenyl-3-methylpyrazolone and barbituric acid, at 60 DEG C. to 200 DEG C. optionally in presence of an inert solvent, e.g. methyl glycol, isobutanol, N-methylpyrrolidone and dimethylformamide. The products are colourless, yellow, yellow-orange or red crystals having m.ps. above 170 DEG C.ALSO:3-Iminophthalimidine hydrochloride and the 6-phenyl and 6-nitro derivatives thereof are prepared from phthalodinitrile or a corresponding derivative thereof by reaction with aqueous alcoholic hydrochloric acid with stirring at temperatures up to 60 DEG C. |
isCitedBy | http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-4066653-A |
priorityDate | 1964-09-25-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 58.