http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1110940-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_47becd0bad1e8c65826be1edac09d306 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2527-1206 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2527-126 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2527-1213 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C7-152 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2-68 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C309-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C15-107 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C2-70 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C15-107 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C2-68 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C7-152 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C15-02 |
filingDate | 1965-10-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1968-04-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1110940-A |
titleOfInvention | Preparation of alkylaromatic hydrocarbons suitable for biodegradable detergent manufacture |
abstract | Detergent alkylate is obtained by cracking a petroleum fraction boiling within the range 300-600 DEG C. to yield long chain olefins, separating a fraction in the C8-C15 range, treating with urea in the presence of a solvent to adduct n-olefins, decomposing the adduct in an aromatic hydrocarbon and subjecting the olefin-aromatic mixture to alkylation in the presence of a Friedel-Crafts catalyst. The feed is cracked at 550-650 DEG C. and 1-5 atmospheres in the presence of steam in a hydrocarbon to steam weight ratio of 8-12:1 and a space velocity of 10-70 kg. of total feed/litre of reactor space/hour. The amount of urea used is 3.5-5 parts per part by weight of adductable hydrocarbon together with 0.5-1.2 parts of solvent, e.g. methanol, per part of urea at 0-35 DEG C. The adduct is decomposed by heating in benzene to 50-80 DEG C. to give an aromatic olefin mol ratio of 4-8:1. The alkylation catalyst may be AlCl3 . HCl, BF3 . HF or HF. |
priorityDate | 1964-10-20-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 31.