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filingDate 1965-04-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_5aae682f84d7ba2a3c3f594014e22c23
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publicationDate 1968-03-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1107101-A
titleOfInvention Alkyl aromatic hydrocarbons suitable for preparing oil-solublc sulfonates and processes for preparing the same
abstract Alkylate suitable for preparing oil-soluble sulphonates is obtained by polymerizing mainly to dimer a C3-C18 olefin in the presence of an acidic or Friedel-Crafts catalyst, alkylating an aromatic hydrocarbon with the polymer in the presence of a Friedel-Crafts catalyst and recovering from the product an alkylate boiling above 325 DEG F. at 20 mm. Hg. pressure and having a molecular weight above 320 and a "mono" (i.e. neglecting alkyl groups in the aromatic hydrocarbon alkylated) branched chain alkyl aromatic content greater than 50% mol. The olefin may be a C5-C12 gasoline obtained by polymerizing propylene or propylene tetramer and is dimerized with sulphuric acid at -10 DEG to 75 DEG C. or preferably with catalyst sludge from the alkylation step in an amount of 0.25-4 parts per part by wt. of olefin at 15-75 DEG C. In the latter case the entire reaction product passes to the alkylation. The aromatic hydrocarbon may be benzene, toluene, xylene, ethylbenzene or naphthalene or a refinery aviation blending component in an amount of 0.2-10 parts per part by wt. of olefin fed to the dimerization. Preferred catalyst is a promoted aluminium chloride in an amount of 0.02-0.25 part per part by wt. of olefin feed. Reaction is effected at 5-75 DEG C.
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priorityDate 1964-05-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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