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filingDate 1965-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1968-01-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1098636-A
titleOfInvention Catalystic process for making polyesters
abstract In the manufacture of polyesters by reacting a dicarboxylic acid (or ester-forming derivative thereof) with a glycol of formula HO-(CH2)n-OH, where n = 2 to 10, and then polycondensing the resulting product, there is used as a polycondensation catalyst an antimonyl derivative of a polyhydric phenol containing an orthodihydroxy grouping. Many aliphatic and aromatic dicarboxylic acids are mentioned. Specified catalysts are those made by reacting antimony trichloride with pyrogallol, catechol, p-phenyl catechol, 4:6-dimethyl catechol, 4-methyl catechol, 4-methyl-6-butyl catechol, 4-tert. butyl catechol, 1:2-dihydroxy naphthalene, 4-chlorocatechol and gallic acid. Polycondensation may also be effected in the presence of certain polyphosphonate or phosphitepolyphosphonate compounds as stabilizers or certain chain-branching agents. Examples describe the preparation of polyethylene terephthalate from ethylene glycol and free terephthalic acid using as catalyst o-phenylene antimonate or a mixture thereof and the corresponding chloride. Reference has been directed by the Comptroller to the Specification 740,381.
priorityDate 1964-08-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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