http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1089345-A
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_794c0541eeb177127ba84aa959f0316a |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G65-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G65-266 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G65-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G65-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G65-2654 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/D01F6-66 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G65-26 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G65-22 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G65-14 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G65-12 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/D01F6-66 |
filingDate | 1965-01-05-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1967-11-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | GB-1089345-A |
titleOfInvention | Process for the polymerization and copolymerization of compounds containing epoxy groups |
abstract | Homopolymers of alkylene oxides and copolymers of alkylene oxides with olefinically unsaturated monoepoxides are prepared by polymerizing the monomers in the presence of a solvent and, as catalyst, an aluminium compound of formula Al.H.X.Y.Z, where X and Y are hydrogen, halogen or secondary aliphatic or aromatic amine residues, and Z is an ether or tertiary amine, and can be dispensed with when X and/or Y is a secondary amine residue. An elastomer may be prepared from propylene oxide allyl glycidyl ether copolymers, of the type obtained by the above process, by sulphur-curing copolymers containing 1.5 to 6% of allyl glycidyl ether units and which elastomer has a high structural regularity, as evidenced by X-ray crystallography, is capable of being crystallized under traction and has a tensile strength of at least 200 kgs./cm.2. The catalyst for the polymerization process may be used in conjunction with chelating agents and/or water. The solvent is benzene, toluene or an aliphatic or cycloaliphatic hydrocarbon. Specified catalysts are aluminium trihydride, or monochloro- or dichloroaluminium hydrides, all of which have been formed into complexes with ethers or amines, monochloromonoamino - aluminium hydride, dimethylamino - aluminium hydride, and piperidino aluminium dihydride. Suitable chelating agents are acetylacetone, diacetone mono-oxime, dimethylglyoxime, acetonylacetone. Specified monomers are ethylene oxide, propylene oxide, butylene oxide, butadiene monoxide, vinyl glycidyl ether, allyl glycidyl ether, glycidyl acrylates, glycidyl methacrylates, and epichlorohydrin. |
priorityDate | 1964-01-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 62.