http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1082784-A

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C245-08
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filingDate 1966-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1967-09-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1082784-A
titleOfInvention Hydrazo-compounds
abstract A hydrazo-aromatic compound is obtained by reducing an aromatic nitro-compound in the presence of strong alkali (optionally in the presence of quinones) and an aliphatic and/or cycloaliphatic glycol or polyol having from 2 to 12 carbon atoms. A carboxylic acid is obtained as a by-product. Specified glycols which may be used are ethylene glycol, 1,2-propylene glycol, di- and tri-ethylene glycols, butane-1,2-diol, butane-2,3-diol, pentane-1,2,-diol, hexane-2,3-diol, cyclohexane-1,2-diol and mixtures of various polyethylene glycols obtained as by-products in the preparation of ethylene glycol. Specified polyols are glycerol and hexane-1,2,4-triol. Specified quinones are 2-hydroxy-1,4-naphthoquinone, 1,4-naphthoquinone and derivatives of 1,2- and 1,4-naphthoquinone. Specified organic solvents which may be used as diluents are dioxan, tetrahydrofuran and methanol. Examples are given for the production of hydrazobenzene and hydrazotoluene together with sodium oxalate and/or glycollate as by-product.
priorityDate 1965-04-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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