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filingDate 1963-01-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f0fd979d9fce7e160c3db5ea678b55b1
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publicationDate 1967-03-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1061081-A
titleOfInvention The oxidation of hydrocarbons
abstract Aliphatic or cycloaliphatic hydrocarbons are oxidized at elevated temperature and in the liquid phase with oxygen in the presence of a catalytic amount of an alkoxide of a metal of Groups III, IV or V of the Periodic Table, to compounds such as alcohols, ketones, carboxylic acids and esters. Alkoxides with up to 6 C atoms are preferred and they may be prepared in situ. A transition metal salt may be included e.g. a naphthenate, palmitate or stearate. Examples describe the oxidation of dodecane, and cyclohexane using aluminium triethoxide and n-dodecanol-1-vanadate with cobalt naphthenate, and n-propyl-0-titanate and cobalt naphthenate respectively as catalysts, and also the oxidation of n-dodecane using thallic alkoxide formed in situ with the C12 alcohols formed in the reaction with cobalt naphthenate.
priorityDate 1963-01-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 32.