http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1045813-A

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C323-00
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filingDate 1964-10-02-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d314cec12af1e0e30acb868fab1fdc84
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_3f64c0d72af91c1342613008a019b153
publicationDate 1966-10-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1045813-A
titleOfInvention Sulphurised phenols
abstract The invention comprises sulphurized phenols prepared by heating sulphur with a phenol in the presence of a Friedel-Crafts catalyst. The compounds probably contain 2-5 phenol nuclei bridged by mono- or di-sulphide linkages predominantly in the o-position. Suitable phenols for use as starting materials are phenol itself, dihydroxybenzenes, naphthols, dihydroxybiphenyls and phenols containing aryl, aryloxy or aralkyl groups attached to the aromatic nucleus, e.g. a phenylphenol or a -methylbenzylphenol. Suitable catalysts are, for example, aluminium chloride, aluminium bromide, ferric chloride, zinc chloride and stannous bromide. Preferably 0.5 to 5 atomic proportions of sulphur are used to one molecular proportion of phenol.ALSO:Sulphurized phenols prepared by heating sulphur with a phenol in the presence of a Friedel-Crafts catalyst may be used as anti-oxidants in rubber. The sulphurized phenol may be incorporated into the rubber before or after vulcanizing and may be used for synthetic or natural rubber. Examples are given of the use of a sulphurized phenol as an natioxidant in a white rubber stock before vulcanizing and in a vulcanized rubber stock.
isCitedBy http://rdf.ncbi.nlm.nih.gov/pubchem/patent/US-3717682-A
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type http://data.epo.org/linked-data/def/patent/Publication

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