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filingDate 1964-01-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_96cef8dcf3646d87340898759706315d
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publicationDate 1966-09-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1043360-A
titleOfInvention Production of homopolymers and copolymers of unsaturated hydrocarbons
abstract Homopolymers and copolymers of unsaturated cyclic hydrocarbons (other than aromatic hydrocarbons) are produced by polymerizing them under oxidizing conditions alone or with another unsaturated cyclic hydrocarbon and/or an open-chain diolefin and/or a compound having an aromatic ring system at temperatures of from -30 DEG to 150 DEG C. and in the presence of a Friedel-Crafts catalyst. Cyclic unsaturated hydrocarbons specified are cyclooctene, cyclopentadiene, dicyclopentadiene, cyclohexadiene, cycloheptatriene, cyclooctadiene-1,3, cyclooctadiene-1,5, cyclooctatriene, cyclooctatetraene, and cyclododecatriene. Comonomers exemplified are benzene, thiophene, isoprene, quinaldine, anthracene and phenanthracene. A number of catalyst components are specified; those exemplified are Friedel Crafts catalysts-AlCl3 and TiCl4, oxidizing agents-CuCl2, FeCl3, PbCl4 and PbNO3. Polymerization may be effected in a diluent or preferably in bulk. Traces of water or alcohols may advantageously be present in the reaction mixture. The polymers formed have semiconductor properties.
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priorityDate 1963-02-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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