http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1025422-A

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http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G63-68
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publicationDate 1966-04-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1025422-A
titleOfInvention Copolyesters and the preparation thereof
abstract Polymers containing carbonate and phosphonate linkages are made by condensing (a) an alkali metal diphenate, (b) phenyl phosphoric acid dichloride and (c) phosgene and/or a dichloroformate of a dihydric phenol; the diphenate being dissolved in water and the other reactants being dissolved in a water-immiscible organic liquid which is a solvent or swelling agent for the polymer. The reaction mixture may also include thiophosgene, terephthaloyl chloride, isophthaloyl chloride, phthaloyl chloride, sebacyl chloride, adipyl chloride or 4:41-diphenylether dicarboxylic acid chloride. Condensation is effected in the presence of a quaternary ammonium, phosphonium or arsonium compound or a ternary sulphonium compound. A large number of dihydric phenols are specified but the ones used in the examples are bisphenol A and a mixture of isomeric bis-(hydroxyphenyl)-methanes. Some of the polymers are soluble in chlorinated aliphatic hydrocarbon, toluene, xylene, tetrahydrofurane and dioxane. They are useful in the manufacture of films, threads and surface coatings.
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