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filingDate 1964-03-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1965-12-31-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber GB-1015217-A
titleOfInvention Self-extinguishing resins containing free radical initiators
abstract An alkenyl aromatic polymer composition containing a halogen flameproofing agent also contains a free radical initiator which is a sulphenamide, a hydrazone, an organic disulphide, an azo compound, a quinone imine, or a -a 1-diphenyl-a -methoxybibenzyl as a flameproofing adjuvant. In the examples 28 different free radical initiators and 10 different halogen flameproofing agents are used. Polymers exemplified are polystyrene, polyvinyl toluene, and copolymers of styrene with a -methyl styrene, acrylonitrile or butadiene. Other polymers specified include polychlorostyrene. The adjuvants are incorporated in the polymer composition by dissolving the ingredients in a common solvent, e.g. methyl chloride, and then rapidly evaporating the solvent to give a foamed structure; by impregnation under pressure of polymer granules with the adjuvants in aqueous emulsion (and optionally with a blowing agent such as n-pentane if a foamable resin is required); or, in the case of those adjuvants that do not generally inhibit polymerization, by polymerization of the alkenyl aromatic monomers in the presence of the adjuvants.
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