http://rdf.ncbi.nlm.nih.gov/pubchem/patent/GB-1009312-A
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_e1b426957d11577837cc5ce64f121025 |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-14 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C67-03 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-76 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C67-03 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C69-773 |
| filingDate | 1964-08-04-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationDate | 1965-11-10-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | GB-1009312-A |
| titleOfInvention | Improvements in or relating to the preparation of esters |
| abstract | Aryl esters of carbocyclic mono- or poly-carboxylic acids are prepared by reacting an aliphatic ester of the acid, containing at least 2 carbon atoms in the aliphatic group, with a monohydric phenol at a temperature above 160 DEG C. in the presence of a transesterification catalyst, the aliphatic alcohol produced being removed from the reaction mixture as it is formed. The treatment of esters of di- or polycarboxylic acids having carboxy groups in adjacent nuclear positions is excluded. When esters of dicarboxylic acids are treated, the process may yield either diaryl esters of the acids or aryl-alkyl esters, the relative quantities of the reagents or the duration of the reaction being suitably adjusted. Specified transesterification catalysts are polyphosphoric acids, alkali-metal hydrogen phosphates, alkali or alkaline-earth metal hydroxides, tertiary amines, butyl titanate, calcium stearate, zinc laurate and compounds of antimony or tin, e.g. antimony trioxide or tin stearate. In typical examples, (1) ethyl benzoate and phenol, in the presence of butyl titanate, yield phenyl benzoate, (2) butyl p-toluate and phenol, in the presence of tin stearate and zinc stearate, yield phenyl p-toluate, (3) dibutyl terephthalate and phenol, in the presence of antimony trioxide, yield butyl phenyl terephthalate and diphenyl terephthalate, (4) propyl hexahydro-p-toluate and phenol, in the presence of tin stearate, yield phenyl hexahydro-p-toluate and (5) dibutyl isophthalate and m-cresol, in the presence of antimony trioxide, yield butyl m-cresyl isophthalate and di-m-cresyl isophthalate. Other acids from which the initial esters may be derived are diphenyldicarboxylic acids, diphenylmethane-dicarboxylic acids, benzophenonedicarboxylic acids, naphthalenedicarboxylic acids, and cyclohexanedicarboxylic acids. Other phenols which may be used are the xylenols, butyl phenols, octyl phenols, benzyl phenols and b -naphthol. |
| priorityDate | 1963-08-03-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 75.