http://rdf.ncbi.nlm.nih.gov/pubchem/patent/FR-3011236-A3

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publicationDate 2015-04-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber FR-3011236-A3
titleOfInvention SILICON ALLOY INJECTION METHOD BY VACUUM INERTAGE SAS FOR CONTINUOUS GENERATION OF SILANE
abstract Process for the preparation of a compound or a mixture of compounds of formula SinH2n + 2 in which n is an integer greater than or equal to 1 and less than or equal to 3, comprising a step a) of reacting at least one silicide or silicon alloy selected from alloys of formula M1xM2ySiz where M1 is a reducing metal and M2 is an alkaline or alkaline earth metal, with hydrochloric acid previously dissolved in a solvent, characterized in that said preparation is provided by a regular injection of alloy and hydrochloric acid, the method comprising a step b) of regular withdrawal of the reactive solution for controlling the reaction volume, and characterized in that the at least one silicide or silicon alloy is previously injected into a reactor through a vacuum inert lock chamber.
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