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filingDate 1996-12-03-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 1998-06-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber FR-2756500-A1
titleOfInvention CATALYTIC SYSTEM CONTAINING OXYGEN, MOLYBDENUM AND PHOSPHORUS, AND ITS APPLICATION TO THE OXIDESHYDROGENATION OF SATURATED CARBOXYLIC ACIDS OR THEIR ESTERS, AS WELL AS ALKANES OXIDATION
abstract Catalytic system based on a product represented by the formula Csx (NH4) 3-x PMo12 O40 Mey (VO) z in which Me la represents an ion of a transition metal chosen from copper, cobalt, iron, silver, nickel and manganese, or a magnesium ion; o = <x = <3; o = <y = <3; o = <z = <3, and prepared by reacting an aqueous solution of H3-t Nat PMo12 O40, with o = <t = <3, with an ammonium salt and / or a cesium salt with precipitation of ammonium and / or cesium salt Csx (NH4) 3-x PMo12 O40, x being as defined above; optionally adding to the aforementioned salt of an aqueous solution of a salt of Me and / or of a salt of vanadyl; drying of the compound obtained until complete evaporation at a temperature of 90-200 deg. C for a period of 2 to 16 hours, then calcination at a temperature of 250-400 deg. C for a period of 2 to 24 hours; and shaping of the resulting pulverulent product of formula (I) by compression of powders, pelletizing, granulation, extrusion or coating on a support, to obtain said catalytic system in the form of pellets or grains.
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