http://rdf.ncbi.nlm.nih.gov/pubchem/patent/FR-2309533-A1
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_d202e9e866984fe229f6facc38f1d740 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D489-02 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07D489-02 |
filingDate | 1975-05-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1976-11-26-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | FR-2309533-A1 |
titleOfInvention | THEBAINE PREPARATION PROCESS |
abstract | Thebaine is produced in high yield by (a) reacting either or both the epimeric salutaridinols with a 2-4C aliphatic acid anhydride or with SOCl2, SOBr2, POCl3, POBr3, PBr3, PCl3, PCl5, PBr5, COCl2, CH3SO2Cl and SO2, CH3SO2Br, ClCO2CH3, ClCO2CH2Ph or p-dinitrophenylchlorocarbonate opt. in the presence of an additional tert. amine and (b) treating the prod. obtd. with an alkali metal hydroxide, carbonate or phosphate. Pref. the reaction is effected at -10 to +25 degrees C. The epimeric mixt. is partic. obtd. by NaBH4 redn. of salutaridine. |
priorityDate | 1975-05-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 38.