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filingDate 1968-12-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1970-08-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-361141-A1
titleOfInvention CONTINUOUS PROCEDURE FOR THE OBTAINING OF N-METHYL-ALKYLAMINES.
abstract Oxidic Zn-Al or Zn-Cr catalysts in lump form are used in a process for the preparation of N-methyl-amines wherein a mono- or dicarboxylic acid, which does not form an internal anhydride under the reaction conditions, is hydrogenated at 200-400 C and 50-400 atmospheres pressure in the presence of an excess of mono- and/or dimethylamine or of methanol and ammonia from which said amines may be formed. The catalysts used in the Examples are prepared (a) by mixing pulverulent ZnO and Al(OH) 3 in water to give a paste which is dried, ground mixed with graphite and moulded into tablets and (b) by mixing ZnO and Cr 2 O 3 in water to a paste which is dried, ground, mixed with graphite and moulded into tablets, then reduced with H 2 .
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