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filingDate 1968-07-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationDate 1970-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-356318-A1
titleOfInvention PROCEDURE FOR DEACTIVATING METALLIC SURFACES.
abstract 4,5,6,7 - Tetrahydrobenzotriazole is prepared by reduction of benzotriazole or N - hydroxybenzotriazole using molecular hydrogen and a metal hydrogenation catalyst. It is preferred to effect reduction using an excess of hydrogen at 25 -200 C. under superatmospheric pressure by vigorous agitation of the benzotriazole in an inert solvent in a sealed reactor. Specified metal catalysts are Rh, Ni, Pd and Pt and mixtures thereof. The metal may be supported on a conventional carrier. It is preferred to subject the benzotriazole compound to a pre-treatment to remove sulphur and other hydrogenation catalysts poisons therefrom. The pre-treatment may comprise agitation of a solution of the compound with a desulphurization or hydrogenation catalyst, e.g., Pt, Pd, Rh, Ni, Fe, Co or Zn metal. In examples a Rh/charcoal hydrogenation catalyst is used.
priorityDate 1967-07-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 30.