http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-349312-A1
Outgoing Links
Predicate | Object |
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assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_1374dd16777534b65ad4422333245af8 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T428-31565 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/Y10T428-31786 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J2321-00 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-4211 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-4227 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-67 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08J5-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08G18-698 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-69 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08J5-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-42 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08G18-67 |
filingDate | 1968-01-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationDate | 1969-05-01-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | ES-349312-A1 |
titleOfInvention | A PROCEDURE TO INCREASE THE ADHERENCE TO RUBBER OF AN ARTICLE MADE OF A CRYSTAL POLYESTER. |
abstract | Polyester-polyurethanes are prepared by reacting an organic disiocyanate, an ethylene terephthalate polyester or ethylene-2,6-naphthalene polyester and a difunotional chain extending agent so that the portions of polyester constitute 1/6 to 5/6 of the weight of the polyester-polyurethane and the remainder of the polymer contains at least one ethylenically unsaturated bond per 500 of the molecular weight of the polyester-polyurethane. The reaction is preferably carried out in the presence of a solvent. The ethylenically unsaturated bonds are suitably introduced into the polyurethane using a diol having ethylenic unsaturation in place of whole or part of the difunctional chain extending agent. Suitable such diols are alkene diols, unsaturated polyesters or unsaturated polyethers having a low degree of polymerization, poly(diene) glycols, poly(diene) dicarboxylic acids, bis-epoxypoly(dienes) and polyisoprene dicarboxylic acids. Water dispersibility of the polyester-polyurethane may be improved by incorporating a tertiary amino group into the polymer and neutralizing such a group with an acid. In a typical example, polyethylene terephthalate copolymerized with pentaerythritol is dissolved in nitrobenzene together with a polybutadiene glycol and dibutyl tin dilaurate and to the resultant solution is added diphenylmethane diisocyanate to form a copolymer which is precipitated with methanol. The polyester-polyurethanes are used to coat polyester articles, which coated articles are adhered to rubber (see Divisions B2 and D1). |
priorityDate | 1966-02-02-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 36.