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filingDate 2016-12-07-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-03-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2022-03-14-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2899827-T3
titleOfInvention Tin-containing zeolitic material having a BEA framework structure
abstract A process for preparing a zeolitic material containing tin and having a BEA-type structure, comprising (i) providing a zeolitic material with a BEA-type structure in which the structure comprises B2O3 and SiO2, in which said structure has sites vacant tetrahedral structure; wherein according to item (i), the zeolitic material with a BEA-type structure having vacant tetrahedral framework sites is provided by means of a process comprising (i.1) providing a zeolitic material having a framework of type BEA, in which the framework of the starting zeolitic material comprises B2O3 and SiO2 and the molar ratio B2O3 : SiO2 is greater than 0.02 : 1. (i.2) creating vacant tetrahedral framework sites by treating the material zeolitic provided in item (i.1) with a liquid solvent system, to obtain a zeolitic material having a B2O3:SiO2 molar ratio of at most 0.02:1, in which the liquid solvent system does not contain a inorganic acid and an organic acid and a salt thereof, wherein the liquid solvent system is selected from the group consisting of water, monohydric alcohols, polyhydric alcohols, and mixtures of two or more thereof; (ii) providing a liquid aqueous mixture comprising a source of tin ions and an acid, wherein the source of tin ions according to item (ii) is one or more of the tin (II) salts of organic acids having 1 to 6 carbon atoms, wherein the acid comprised in the liquid aqueous mixture provided in item (ii) is one or more organic acids; (iii) preparing a mixture of the zeolitic material provided in item (i) and the aqueous mixture provided in item (ii), to obtain a tin-containing zeolitic material having the BEA framework type, in which the ratio between the volume of the aqueous mixture divided by the mass of the zeolitic material, in cm3/g, and the TPV is in the range of 0.1:1 to 1.7:1, where the TPV is the total volume of pores of the zeolitic material in cm3/g determined by means of nitrogen absorption according to DIN 66134; (iv) drying the zeolitic material obtained from item (iii).
priorityDate 2015-12-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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