http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2899188-T3

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filingDate 2016-05-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2022-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ec6e11506c9bd97cf369c49acbde0534
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6359bdf31cbb6aa1bde5ca718629044d
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publicationDate 2022-03-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2899188-T3
titleOfInvention RAFT agent, polymerization procedure, polymer and rubber mixture, as well as its use
abstract RAFT agent of formula I) I) Z-C(=S)-S-R-S-P, in which Z is a typical Z group for RAFT polymerization and is selected from a) phenyl, b) phenoxy, c) alkoxy with 1 to 30 atoms of carbon, d) alkyl with 1 to 30 carbon atoms, e) S-alkyl with 1 to 30 carbon atoms, the bonding to the -C(=S)-S-R-S-P moiety of the RAFT agent taking place through the atom of sulfur, f) heterocyclic groups, g) alkyl(phenyl)amino with 1 to 30 carbon atoms, the linking to the -C(=S)-S-R-S-P moiety of the RAFT agent taking place through the nitrogen atom, h) dialkylamino with 1 to 30 carbon atoms in each alkyl chain, with all groups bonding to the -C(=S)-S-R-S-P moiety of the RAFT agent through the nitrogen atom and the two groups may be alkyl equal to or different from each other, and in which R is a typical R group for RAFT polymerization and is selected from a) cyanoisopropyl, b) 2-phenylpropan-2-yl, c) cyano(phenyl)methyl, d) 1 -ethoxy-2-methyl-1-oxopropan-2-yl or e) 2,4,4-trimethylpentan-2-yl, f) 1-cyanoethyl, g) 1-phenylethyl, h) tert-butyl, i) cyanomethyl, j) benzyl and k) polymethacrylates, which depending on The synthesis can present a carbamate group or a dithiocarbamate group, the bonding to the Z-C(=S)-S- moiety of the RAFT agent taking place through the secondary carbon atom of the first methacrylate unit of the polymethacrylate group, and in which C is a carbon atom, and where S is a sulfur atom, and where P is a protecting group, which is selected from the group consisting of S(=O)2-R1 where R1 = alkyl, benzyl, or phenyl and S-C(=S)-N-R2R3 where R2 and R3 = alkyl, benzyl or phenyl and C(=O)-R4 where R4 = alkyl and N-R5R6 where R5 = hydrogen atom (H), alkyl, benzyl or phenyl and R6 = alkyl, benzyl or phenyl and SiR7R8R9 where R7, R8 and R9 = alkyl or benzyl and S(=O)2-OM where M = Na, K or H.
priorityDate 2015-05-12-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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