http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2875151-T3

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assignee http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_e2ed31ee9354301da12dc9a7e9e03df1
classificationCPCAdditional http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C2601-16
classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07C403-20
classificationIPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07C403-20
filingDate 2016-03-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d96e2206292b2f079969cbfb987cb71e
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_84be6978e941719d2c0ab9d9f7c3e36e
publicationDate 2021-11-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2875151-T3
titleOfInvention Procedures for the preparation of unsaturated malonates
abstract A process for the preparation of an unsaturated malonate, or any stereoisomer thereof, comprising the steps of carrying out a reaction between an aldehyde of formula A and a dialkyl malonate of formula B: **(See formula)** in which each one of R1 and R2 independently is selected from the group consisting of C1-C20 linear or branched alkyl, C2-C20 linear or branched alkenyl, and C2-C20 linear or branched alkynyl, and R3 and R4 are each independently selected from the group consisting of linear or branched C1-C4 alkyl; wherein the reaction is carried out in the presence of a Lewis acid and a carboxylic acid; thereby forming a product containing an unsaturated malonate of formula C: **(See formula)** and the Lewis acid is a compound of formula MXn, wherein M is a metal selected from group IA or IIA; X is a halogen; and n is 1 or 2, where the term "alkenyl" refers to a linear or branched hydrocarbon group of 2 to 20 carbon atoms and one or more double bonds and the term "alkynyl" refers to a linear or branched hydrocarbon group 2 to 20 carbon atoms and one or more triple bonds.
priorityDate 2015-03-11-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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