http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2857699-T3

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filingDate 2017-10-20-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2021-09-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_f90c0e37998f4d87b5862821eafbc46a
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_236654432b444f210645d8c2e9523cf6
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publicationDate 2021-09-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2857699-T3
titleOfInvention A crystalline organometallic framework
abstract A crystalline organometallic framework comprising repeating units of formula (IA), or alternatively a crystalline organometallic framework comprising repeating units of formula (IB), comprising one metal of M2 + and two ligands L1- ** (See formula) ** where: the two L1- ligands may be the same or different, M2 + is a divalent metal cation, each L1- is an anion independently selected from the group consisting of (R) - (imidazol-5-ylmethyl) - (1 , 2,4-triazol-4-yl) acetate of formula (R) - (II) and (S) - (imidazol-5-ylmethyl) - (1,2,4-triazol-4-yl) acetate of formula (S) - (II); ** (See formula) ** in the repeating unit of formula (IB), the metal M is coordinated with two solvent molecules S, both S are the same and are a solvent molecule selected from the group consisting of water, methanol , ethanol, isopropanol, tert-butanol, diethyl ether, 1,4-dioxane, tetrahydrofuran, N, N-dimethylformamide, acetonitrile, acetone, 1,2-ethylene glycol, dimethylsulfoxide and pyridine, → represents a coordination bond between the metal M2 + and a nitrogen atom from each L1- ligand; wherein one of the coordination bonds is between the metal M2 + and the nitrogen atom N1 of an L1-; and the other coordination bond is between the metal M2 + and the nitrogen atom N2 of the other L1-; and between the metal M2 + and the solvent molecules S; therefore, the repeating unit has the formula (RR) - (IA), or alternatively, the formula (SS) - (IA) ** (See formula) ** or alternatively, the formula (RS) - (IA), or alternatively, the formula (SR) - (IA) ** (See formula) ** or alternatively, the formula (RR) - (IB), or alternatively, the formula (SS) - ( IB) ** (See formula) ** or alternatively, the formula (RS) - (IB), or alternatively, the formula (SR) - (IB) ** (See formula) ** where each unit of repeat in the organometallic framework is connected to other repeating units in such a way that the M2 + metal of a repeating unit is connected to two additional repeating units of formula (IA), or alternatively of formula (IB), by linkages of coordination represented by between the metal M2 + of the first repeating unit and the nitrogen atoms of ** (See formula) ** the L1- ligands of the additional repeating units, where one of the additional coordination bonds is between the metal M2 + de l a first repeating unit and the nitrogen atom N1 of an L1- of an additional repeating unit; and the other additional coordination bond is between the metal M2 + of the first repeating unit and the nitrogen atom N2 of an L1- of another additional repeating unit.
priorityDate 2016-10-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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