http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2768680-T3
Outgoing Links
Predicate | Object |
---|---|
assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_2a819eda0adf22936a52362eeebb9fb4 |
classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D2253-204 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-46 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-48 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J2531-49 |
classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-003 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D53-047 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-1691 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D53-228 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J20-226 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J37-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D33-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01D63-02 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J20-3085 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/B01J31-00 |
classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01D33-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/B01J31-00 |
filingDate | 2015-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
grantDate | 2020-06-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_b92246fff9fa0a7fac396a8b17a0818e http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_21628e3375d6a0236ac998df4fe1d496 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_544ddd5335e7bb3080df1822f37a2cf6 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2faa50fe6a2e4b8668d792c0288afe0a |
publicationDate | 2020-06-23-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
publicationNumber | ES-2768680-T3 |
titleOfInvention | Organometallic frames that have resistance to acids, solvents, and thermal |
abstract | An organometallic framework (MOF) having thermal, acid, and / or solvent resistance comprising a plurality of connected MOL secondary bonding units (SBU), wherein M is a zirconium or hafnium metal, a metal ion zirconium or hafnium, or a complex containing zirconium or hafnium metal; O is an oxygen atom of a carboxylate-based connecting cluster; and L is an organic linker ligand comprising one or more structures of Formula I to IX and XI to XXII, wherein the linker ligand forms a bond with the metal, metal ion, or metal-containing complex through the carboxylate-based linker cluster. : ** Formula ** where, A1-A8 are independently a C, N, O, or S; A9 is selected from ** Formula ** X1-X8 are independently selected from H, D, alkyl, alkenyl, alkynyl, aryl, heteroalkyl, heteroalkenyl, heteroalkynyl, cycloalkyl, cycloalkenyl, heteroaryl, heterocycle, halo, hydroxyl, anhydride, carbonyl, carboxyl, carbonate, carboxylate, aldehyde, haloformyl, ester, hydroperoxy, peroxy, ether, orthoester, carboxamide, amine, imine, imide, azide, azo, cyanate, isocyanate, nitrate, nitrile, isonitrile, nitroso, nitro, nitrosooxy, pyridyl, sulfhydryl, sulfide, disulfide, sulfinyl, sulfo, thiocyanate, isothiocyanate, carbonothioyl, phosphine, phosphono, phosphate, Si (OH) 3, Ge (OH) 3, Sn (OH) 3, Si (SH) 4, Ge (SH) 4, AsO3H, AsO4H, P (SH) 3, As (SH) 3, SO3H, Sn (SH) 4, C1-C20 alkyl, C1-C19 heteroalkyl, C1-C19 alkenyl, C1-C19 heteroalkenyl, C1-C19 alkynyl , C1-C19 heteroalkynyl, C1-C19 cycloalkyl, C1-C19 cycloalkenyl, aryl, mixed ring system, wherein one or more adjacent R groups can be connected to each other to form one or more rings selected from cycloalkyl, cycloalkenyl, heterocycle, aryl, and mixed ring system; R37, R39, R48 and R52 are hydroxyls; and R1 to R36, R38, R40 to R47, R49 to R51, R53 to R64 and R69 to R186 are independently selected from H, D, alkyl, alkenyl, alkynyl, aryl, heteroalkyl, heteroalkenyl, heteroalkynyl, cycloalkyl, cycloalkenyl, heteroaryl, heterocycle, halo, hydroxyl, anhydride, carbonyl, carboxyl, carbonate, carboxylate, aldehyde, haloformyl, ester, hydroperoxy, peroxy, ether, orthoester, carboxamide, amine, imine, imide, azide, azo, cyanate, isocyanate, nitrate, nitrile, isonitrile, nitroso, nitro, nitrosooxy, pyridyl, sulfhydryl, sulfide, disulfide, sulfinyl, sulfo, thiocyanate, isothiocyanate, carbonothioyl, phosphine, phosphono, phosphate, Si (OH) 3, Ge (OH) 3, Sn (OH) 3, Si (SH) 4, Ge (SH) 4, AsO3H, AsO4H, P (SH) 3, As (SH) 3, SO3H, Sn (SH) 4, C1-C20 alkyl, C1-C19 heteroalkyl, C1-C19 alkenyl , C1-C19 heteroalkenyl, C1-C19 alkynyl, C1-C19 heteroalkynyl, C1-C19 cycloalkyl, C1-C19 cycloalkenyl, mixed ring system, wherein one or more adjacent R groups can be connected to each other to form one or more rings selected from cycloalkyl, cycloalkenyl, heterocycle, aryl, and mixed ring system; and wherein the framework is thermally stable when exposed to a temperature between 50 ° C and 525 ° C, and / or the framework is chemically stable in the presence of a solvent and / or an acid. |
priorityDate | 2014-02-19-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
type | http://data.epo.org/linked-data/def/patent/Publication |
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