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filingDate 2015-03-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2020-05-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d8824db02615a73be982a10dc14ab131
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d6665aab5674cccb1554e67bb23a3f38
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publicationDate 2020-05-25-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2762664-T3
titleOfInvention Free radical and / or cationic light-induced photopolymerization method
abstract A liquid composition, curable by exposure to light irradiation ranging from λ = 200-900 nm, containing: (a) at least one polymerizable component selected from the group consisting of: (i) an ethylenically unsaturated monomer, the polymerization of which can be effected by free radical polymerization; and / or (ii) an ethylenically unsaturated monomer or an epoxy-containing monomer; which polymerization can be carried out by cationic polymerization; (b) an initiator complex of formula I or II ** Formula ** in which Q1 represents a conjugated polyaromatic system containing two nitrogen atoms whose lone pair of electrons forms a bond with the copper atom; Q2 and Q3 independently represent a conjugated polyaromatic system containing a nitrogen atom whose lone pair of electrons forms a bond with the copper atom; W represents a phosphorus or nitrogen atom; R1, R2, R3, R4, R5 and R6 each independently represent a C6-20 alkyl or C6-10 aryl moiety; wherein the alkyl and / or aryl moieties may individually be further substituted with one or more linear or branched C1-6 alkyl or C6-10 aryl moieties; and where R3 and R4, together with the P, Cu and W atoms, can form a 6 to 8 membered ring; X represents a suitable counterion; preferably BF4-, PF6, SbF6- or Cl-; (c) an iodonium salt of formula (RA) 2I +; wherein each occurrence of RA independently represents a C6-10 aryl moiety; wherein the aryl moiety may individually be further substituted with one or more linear or branched C1-6 alkyl or C6-10 aryl moieties; and provided that, when at least one polymerizable component (a) is an ethylenically unsaturated monomer or a monomer containing epoxy polymerizable by cationic polymerization, the liquid composition further comprises (b) a vinyl cationic initiator having structure III or IV: ** Formula ** wherein R7 represents a linear or branched C1-6 alkyl or C1-10 heteroalkenyl moiety or a C6-10 aryl moiety; and R8 and R9 independently represent a linear or branched C1-6 alkyl moiety or a C6-10 aryl moiety; wherein R8 and R9 together can form a cyclic heteroaryl moiety.
priorityDate 2014-03-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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