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publicationDate 2020-04-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2755903-T3
titleOfInvention Articles molded by rotational molding, and method of manufacture thereof
abstract An article obtained by rotational molding comprising: a polyethylene composition comprising; at least 85 percent by weight of the units derived from ethylene; less than 15 weight percent units derived from one or more α-olefinic comonomers; wherein said polyethylene composition has a density in the range of 0.930 to 0.945 g / cm3 (measured according to ASTM D-792-03, Method B, in isopropanol), a molecular weight distribution (Mw / Mn) (measured according to the conventional GPC method, as described in the description) in the range of 1.70 to 3.50, a melt index (I2) (measured at 190 ° C under a load of 2.16 kg of according to ASTM D-1238-03) in the range of 0.5 to 20 g / 10 minutes, a molecular weight distribution (Mz / Mw) (measured according to the conventional GPC method, as described in the description ) in the range of less than 2.5, vinyl unsaturation (measured according to ASTM D-6248-98) of less than 0.06 vinyls per thousand carbon atoms present in the main chain of said composition, wherein said composition polyethylene is substituted with less than 0.1 long chain branches per 1000 total carbons (determined according to permeation chromatography gel ion coupled with a low-angle laser light scattering detector (GPC-LALLS) or gel permeation chromatography coupled with a differential viscometric detector (GPC-DV)); wherein said polyethylene composition comprises the reaction product of (co) polymerization of ethylene and optionally one or more α-olefinic comonomers in the presence of a hafnium-based metallocene catalyst by means of a gas phase (co) polymerization process in a single stage reactor.
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