http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2726855-T3

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filingDate 2014-12-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2019-10-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_d8b51b973bf73e7aacbc2b4117a0a66d
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publicationDate 2019-10-09-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2726855-T3
titleOfInvention Composition suitable for the production of hard cellular polyurethane or polyisocyanurate plastics
abstract Composition, which is suitable for the production of polyurethane or polyisocyanurate hard cellular plastics, containing at least one isocyanate component, at least one isocyanate-reactive component, at least one foam stabilizer, at least one urethane catalyst and / or isocyanurate, optionally water and / or blowing agent, and optionally at least one flame retardant agent and / or additional additives, characterized in that the composition has as foam stabilizers at least two different classes of polyethersiloxanes, fulfilling a class of polyethersiloxanes, below polyethersiloxanes class 1, formula (I) MaDbD'cD''dTeQf (I), where ** Formula ** R1 = independently of each other the same or different hydrocarbon residues with 1 to 16 carbon atoms, preferably methyl, ethyl, propyl and phenyl, in particular preferably methyl, R2 = independently of each other R1, R3 or R4, R3 = independently of each other the same or different polyether residues of general formula (II), -R5O [CH2CH2O] g [CH2CH (CH3) O] h [CHR6CHR7O] iR8 (II) R4 = independently of one another the same or different residues of formula (IIIa) or general formula (IIIb), * * Formula ** R5 = equal or different divalent hydrocarbon radicals with 1 to 16 carbon atoms, which can optionally be interrupted by oxygen atoms, preferably a radical of general formula (IV) where j = 1 to 8, preferably 3, ** Formula ** R6 and R7 = independently of one another the same or different hydrocarbon radicals with 1 to 16, preferably 1 to 12 carbon atoms, which may optionally be interrupted by oxygen or H atoms, particularly preferably methyl, ethyl, phenyl or H, R8 = independently of one another the same or different hydrocarbon radicals with 1 to 16 carbon atoms, which may optionally be interrupted by urethane functions, -C (O) NH-, -carbonyl or -C (O) O-, or H, preferably methyl, -C (O) Me or H functions, R9 = di organic residue valent, preferably with 2 to 20 carbon atoms, which may optionally be interrupted by one or more oxygen functions or functions of the formula - [SiR1 2-O] k-SiR1 2- where k = 1 to 10 and given possibly have OH functions, particularly preferably divalent organic radicals with 6 to 16 carbon atoms, which may optionally be interrupted by one or more oxygen functions and may have OH functions, a = 2 to 32, preferably 2 to 15, in particular preferably 2, b = 2 to 247, preferably 3 to 150, particularly preferably 4 to 80, c = 0.5 to 35, preferably 1 to 22, particularly preferably from 1.5 to 12, d = from 0 to 6, preferably from 0 to 4, in particular preferably 0, e = from 0 to 15, preferably from 0 to 10, particularly preferably 0, f = from 0 to 15, preferably 0 to 10, in particular preferably 0, provided that N = a + b + c + d + e + f = 5 to 250, preferably m ente = from 5 to 160, in particular preferably = from 8 to 80, g = from 4 to 25, h = from 0 to 10, i = 0, being applicable for polyethersiloxanes of the polyethersiloxane class 1 that at least is present a residue R3, whose molar weight is formed in at least 90% by mass per units - [CH2CH2O] -, and fulfilling a class of polyethersiloxanes, then class of polyethersiloxanes 2, of formula (I), as defined for polyethersiloxanes class 1, provided that in polyethersiloxanes class 2 a = 2 to 32, preferably 2 to 15, in particular preferably 2, b = 2 to 297, preferably 3 to 190, in particular preferably from 4 to 110, c = from 0.3 to 30, preferably from 0.9 to 20, particularly preferably from 1.2 to 10, d = from 0 to 6, preferably from 0 to 4, particularly preferably from 0.1 to 3, e = 0 to 15, preferably 0 to 10, particularly preferably 0, f = 0 to 15, preferably 0 to 10, particularly preferably 0, provided that N = a + b + c + d + e + f = 5 to 300, preferably = 8 to 200, particularly preferably = 10 to 120, g = 5 to 30, h = from 3 to 20 and i = 0, and being applicable for the polyethersiloxanes of the class 2 polyethersiloxanes that at least one residue R3 is present, the molar weight of which is made up of a maximum of 50% by mass per units - [CH2CH2O] - , being present as polyethersiloxanes of the class of polyethersiloxanes 1 those, in which in the residues present R3 more than 70% in moles of the residues R8 are H, and being present as polyethersiloxanes of the class of polyethersiloxanes 2 those, in which in the residues present R3 less than 30% by moles of the residues R8 are H, and the mass ratio of polyethersiloxanes of the polyethersiloxane class 1 to polyethersiloxanes of the polyethersiloxane class 2 in the composition rises from 0.1 with respect to 1 to 1 with respect to 0.1.
priorityDate 2013-12-30-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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