http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2692873-T3

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filingDate 2008-06-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2018-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9b86a7ac4d16cf26c1a1627db3af9c44
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publicationDate 2018-12-05-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2692873-T3
titleOfInvention Method of combating the appearance of haze during the coating of flexible supports with a crosslinkable liquid silicone composition, in a cylinder device
abstract Procedure for combating the appearance of haze ("haze") during the coating of flexible supports comprising the following steps I) and II): I) the preparation of a liquid silicone composition X precursor of silicone coating (s) which it comprises: - at least one polyorganosiloxane A crosslinkable by polyaddition, by dehydrogen condensation, by polycondensation, by the cationic route or by the radical route, - optionally at least one cross-linking organosilicon compound B, - optionally at least one catalyst or photo-primer C whose nature is selected according to the type of reaction considered for said polyorganosiloxane A, - optionally at least one adhesion modulator system K, et - optionally at least one crosslinking inhibitor D; et II) the coating of said liquid silicone composition X on a flexible support with the help of a cylinder coating device, said process being characterized in that in step I) an anti-additive is added to said liquid silicone composition X Mist E ("anti-fog" additive) having the following characteristics: - it is presented in a liquid form, possibly after dilution with the aid of a diluent J ', a solvent J ", or one of the constituents of said composition of Liquid silicone X, and - can be obtained by: 1) reacting, preferably at a temperature between 0 ° C and 200 ° C, one or more compounds selected from the following compounds a) to d): a) an organosilicon resin F ( optionally diluted with the help of a diluent J ', a solvent J "or one of the constituents of said liquid silicone composition X), which comprises at least two siloxyl units in its structure d Selected representatives among those of the formula: - (R1) 3SiO1 / 2 (unit M), - (R1) 2SiO2 / 2 (unit D), - R1SiO3 / 2 (unit T), et - SiO4 / 2 (unit Q), Units in which: - R1 radicals, identical or different, are selected from linear or branched alkyl radicals from C1 to C6, alkenyl radicals from C2 to C4, phenyl, trifluoro-3,3,3 propyl with, as conditions : - that at least one of these units is a T or Q unit, and - that said organosilicon resin F comprises groups ≡SiOH and / or> = SiOR2, the weight content in OH and / or OR2 groups being between 0 , 2 and 10% by weight, R2 being a linear or branched alkyl radical from C1 to C6, b) an organosilicon compound of general formula: R3 dSi X4-d in which R3 is a monovalent hydrocarbon group having 1 at 5 carbon atoms, X is a hydrolyzable group and d has an average value <= 1; c) a partially hydrolyzed condensate L of said organosilicon N; d) a condensate M of said organosilicon resin F with said organosilicon compound N or said condensate L; - with: e) at least one organosiloxane monomer, oligomer and / or polymer G of the formula: ** Formula ** in which: 1 <= f <= 2000, preferably 1 <= f <= 1000. - in the presence: - at least one polycondensation catalyst H, - optionally a charge Z, and - optionally at least one diluent J 'or a solvent J ", and 2) isolating the anti-fog additive E, optionally after removal of the H condensation catalyst and / or devolatilization and / or neutralization.
priorityDate 2007-06-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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