http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2685279-T3

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grantDate 2018-10-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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publicationDate 2018-10-08-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2685279-T3
titleOfInvention Photoelectrochemical cell filter-press type for water oxidation and CO2 reduction
abstract A filter-press type photoelectrochemical cell comprising: a) a cathodic compartment (1) comprising a cathode support structure (150) comprising a cathodic material (4) that acts as a cathode; a first structure of distribution of fluid and gaseous CO2 (6) and a second structure of distribution of fluid and gaseous CO2 (7); one or more cathodic joints (81, 82, 83 and 84), the cathode joints being placed between the cathode support structure (150) and the distribution structures (6, 7) and as lateral ends of the cathodic compartment; wherein the cathode support structure (150) is disposed between the first and second distribution structures (6; 7); b) an anodic compartment (2) comprising an anode support structure (250) comprising an anodic material (5) that acts as an anode; a fluid distribution structure (8) arranged so that the fluid distribution structure (8) is in a portion of the anode compartment closer to the membrane (3) than the anode support structure (250); and one or more anode joints (85 and 86), the anode joints being placed between the anode support structure (250) and the distribution structure (8), and as lateral ends of the anode compartment; and c) an ion exchange membrane (3) disposed between the cathodic compartment (1) and the anodic compartment (2); wherein i) the cathodic material (4) is a porous conductive electrode with an electrocatalytic immobilized CO2 material; ii) the first and second gas and CO2 gas distribution structures (6, 7) and the cathode joints (81, 82, 83 and 84) are arranged so that, during use, they allow the introduction of a catholyte and CO2 gas by separated in the cathode compartment (1) through different input ports (11a, 11b) and let out the catholyte, liquid and gaseous products and / or CO2 not reacted together through an exit port (12); iii) the fluid distribution structure (8), the anode support structure (250) and the anodic joints (85 and 86) are arranged so that, during use, they allow an anolyte to be introduced into the anodic compartment (2 ) through an inlet port (13), and release the anolyte and oxidation products together through an outlet port (14); iv) the anodic material (5) is a photocatalytic anodic material and is located on a membrane-oriented side (3) of an optical window (15) of the anode support structure (250); and is arranged so that, during use, it is capable of being in contact with the anolyte that is introduced into the anodic compartment through the inlet port (13) and is capable of being activated when the radiation used to irradiate the anodic compartment (2) reaches the optical window (15) on its opposite side that is not oriented towards the membrane (3); and v) the photocatalytic anodic material (5) and the cathodic gas diffusion material (4) have a surface area ratio of 1: 1 to 1: 0.1.
priorityDate 2014-12-19-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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