http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2634440-T3

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filingDate 2007-04-24-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2017-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_ab707fb98c37c90cf5ea4164dc02aa86
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publicationDate 2017-09-27-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2634440-T3
titleOfInvention Polymerization process of polyethylene in high temperature solution
abstract A metal complex of a polyvalent aryloxyether corresponding to the formula: ** Formula ** where M3 is Hf or Zr, preferably Zr; Ar4 corresponds to the formula: ** Formula ** in which each R11, independently in each case, is a hydrogen, halogen, hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di (hydrocarbyl) amino of up to a maximum of 50 atoms not counting hydrogen, or two R11 groups together are part of a ring attached to the aryl group at two positions, provided that, in at least one case, the R11 group or the divalent derivative of two such R11 groups is independently select from the group consisting of alkyl-, cycloalkyl-, trihydrocarbylsilyl-, tri (hydrocarbyl) silylhydrocarbyl- and tri (hydrocarbyl) phenyl-tertiary groups having 3 to 20 non-hydrogen or di (hydrocarbyl) amino atoms of up to 50 atoms not counting hydrogen and / or lacks coplanarity with the aryl group to which it is attached; T4, independently in each case, is an alkylene, cycloalkylene or cycloalkenylene group having from 2 to 20 carbon atoms, or is a group derived from them inertly substituted; R21, independently in each case, is a hydrogen, a halogen, a hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or di (hydrocarbyl) amino group of up to a maximum of 50 atoms without counting hydrogen; R3, independently in each case, is a hydrogen, a halogen, a hydrocarbyl, trihydrocarbylsilyl, trihydrocarbylsilylhydrocarbyl, alkoxy or amino group of up to a maximum of 50 atoms without counting the hydrogen atoms, or two R3 groups together in the same arylene ring or an R3 group and an R21 group together in the same or different arylene rings form a divalent ligand group attached to the arylene group at two positions or are attached to two different arylene rings, provided that at least two R3 groups located on Different aryloxy groups are independently selected from the group consisting of alkyl-, cycloalkyl-, trihydrocarbylsilyl-, tri (hydrocarbyl) silylhydrocarbyl- and tri (hydrocarbyl) phenyl-tertiary groups having 3 to 20 non-hydrogen or di ( hydrocarbyl) amino of up to 50 atoms excluding hydrogen or at least one R3 group is a linear alkyl group; and RD, independently in each case, is a halogen, or a hydrocarbyl or trihydrocarbylsilyl group with a maximum of 20 carbon atoms, not counting those of hydrogen, or two RD groups together constitute a hydrocarbylene, hydrocarbadiyl, diene or poly (hydrocarbyl group). ) silylene.
priorityDate 2006-05-17-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 67.