http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2592286-T3

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filingDate 2012-09-28-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2016-11-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6a4044f18ebde26ea7b02f573a63913f
http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9d5bdca8d55388758069b0bdeca594e6
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publicationDate 2016-11-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2592286-T3
titleOfInvention Photolabile latex for perfume release
abstract A polymer microparticle capable of controlled release of a perfuming aldehyde or ketone, said polymer microparticle comprising: a) at least one repeating unit of formula ** Formula ** in which A represents a benzene-1,4-diyl or a benzene-1,3-diyl moiety, and R is a CH (R ') (R ") group corresponding to a perfuming agent: - aldehyde selected from the group consisting of benzaldehyde, 1,3-benzodioxol-5- carboxaldehyde, 3- (1,3-benzodioxol-5-yl) -2-methylpropanal, 3- (4-tert-butyl-1-cyclohexen-1-yl) propanal, 2,4-decadienal, 2-decennial, 4 - decennial, 8-decennial, 9-decennial, 3- (6,6-dimethyl-bicyclo [3.1.1] hept-2-en-2-yl) propanal, 2,4-dimethyl-3-cyclohexene-1- carbaldehyde, 3,5-dimethyl-3-cyclohexene-1-carbaldehyde, 1- (3,3-dimethyl-1-cyclohexyl) -1-ethanone, 5,9-dimethyl-4,8-decadienal, 3- (3 , 3- and 1,1-dimethyl-2,3-dihydro-1H-inden-5-yl) propanal, 2,6-dimethyl-5-heptenal, 3,7-dimethyl-2,6-octadienal, 3, 7-dimethyloctanal, 3,7-dimethyl-6-octenal, (3,7-dimethyl-6-octenyl) acetaldeh Idol, 3-dodecenal, 4- dodecenal, 3-ethoxy-4-hydroxybenzaldehyde, 4-ethyl benzaldehyde, 3- (2 and 4-ethylphenyl) 2,2-dimethylpropanal, 2- furancarbaldehyde, 2,4-heptadienal, 3, 5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbaldehyde, 4- heptenal, 2-hexenal, 3-hexenal, 2-hexyl-3-phenyl-2- propenal, 2-hydroxybenzaldehyde, 7-hydroxy-3,7-dimethyloctanal, 4-hydroxy-3-methoxybenzaldehyde, 4- and 3- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carbaldehyde, 4- isopropylbenzaldehyde , 8-isopropyl-6-methyl-bicyclo [2.2.2] oct-5-eno-2-carbaldehyde, 3- (4-isopropylphenyl) -2-methylpropanal, 2- (4-isopropylphenyl) propanal, 2- and 4 -methoxy-benzaldehyde, 6-methoxy-2,6-dimethylheptanal, 3- (2- methoxyphenyl) acrylaldehyde, 8 (9) -methoxy-tricyclo [5.2.1.0 (2,6)] decane-3 (4) -carbaldehyde , 4-methylbenzaldehyde, 3- (4-methylcyclohex-3-en-1-yl) butanal, 2- (4-methylcyclohexyl) propanal, 1-methyl-4- (4-methyl-3-pentenyl) -3-cyclohexen - 1-carbaldehyde, 3- (4-methyl-3-pentenyl) -3-cyclohexene-1-carbaldehyde, 4- (4-methyl-3-pentenyl) -3-c iclohexene-1- carbaldehyde, (4-methylphenoxy) acetaldehyde, (4-methylphenyl) acetaldehyde, 3-methyl-5-phenylpentanal, 2- (1-methylpropyl) - 1-cyclohexanone, 2-methyl-4- (2 ', 2 ', 3'-trimethyl-3'-cyclopentenyl) -4-pentenal, 2,4-nonadienal, 2,6-nonadienal, 2- nonenal, 3-nonenal, 6-nonenal, 8-nonenal, 2-octenal, 2-pentyl-3-phenyl-2-propenal, phenoxyacetaldehyde, 2- phenylacetaldehyde, 3-phenylbutanal, 3-phenylpropanal, 2-phenylpropanal (hydrotropaldehyde), 3-phenyl-2-propenal, 4- (prop-1-en- 2-yl) cyclohex-1-enocarbaldehyde (perilaldehyde), 3- (4-tert-butylphenyl) -2-methylpropanal, 3- (4-tert-butylphenyl) propanal, tricycle [5.2.1.0 (2,6)] decane-4 -carbaldehyde, exo-tricycle [5.2.1.0 (2,6)] decane-8-exocarbaldehyde, 2,6,6-trimethyl-bicyclo [3.1.1] heptane-3-carbaldehyde, 2,4,6- and 3,5 , 6-trimethyl-3-cyclohexene-1- carbaldehyde, 2,2,3-trimethyl-3-cyclopenten-1-acetaldehyde, 2,6,10-trimethyl-2,6,9,11-dodecatetraenal, 2,5 , 6- trimethyl-4-heptenal, 3,5,5-trimethylhexanal, 2,6,10-trimethyl-9-undecenal, 2-undecenal, 10-undecenal or 9 - undecenal and mixtures thereof, and an aldehyde of the formula (R ") CHO in which R" is a linear or branched C6 to C15 alkyl group, or - ketone selected from the group consisting of an damascenone, an damascone , an ionone or methyl ionone, irone, macrocyclic ketone such as cyclopentadecanone or 3-methyl-4-cyclopentadecen-1-one and 3-methyl-5-cyclopentadecen-1-one or 3-methyl-1-cyclopentadecanone, 1- ( 2-aminophenyl) -1-ethanone, 1- (3,3-dimethyl-1- cyclohexen-1-yl) -4-penten-1-one, 1- (5,5-dimethyl-1-cyclohexen-1- il) -penten-4-1-one, 1- (3,3-dimethyl-1-cyclohexyl) -1- ethanone, 2,5-dimethyl-2-octene-6-one, 4,7-dimethyl-6 -octene-3-one, (3,7-dimethyl-6-octenyloxy) acetaldehyde, 1- (2,4-dimethylphenyl) -1-ethanone, 4- (1,1-dimethylpropyl) -1-cyclohexanone, 2, 4-di-tert-butyl-1-cyclohexanone, 4- oxopentanoate acetate, 1- (4-ethylphenyl) -1-ethanone, 1- (3,5,5,6,8,8-hexamethyl-5.6 , 7,8-tetrahydronaphthalen-2-yl) ethanone, 2- hexyl-1-cyclopentanone, 2-hydroxy-3-methyl-2-cyclopenten-1-one, 4- (4-hydroxy-1-phenyl) -2 -butanone, 1- (2 and 4- hydroxyphenyl) -1-ethanone, 2-isopropyl-5-methylcyclohexanone, 4-isopropyl-2-cyclohexen-1-one, 1- (5-isopropyl-2-methylcyclohex-1- or 2-en- 1-yl) propanone, 1- (4-isopropyl-1-phenyl) -1-ethanone, 2- (2-mercaptopropan-2-yl) -5-methylcyclohexanone, 1- (4-methoxyphenyl) -1-ethanone, 7-methyl-2H, 4H-1,5-benzodioxepin-3-one, 5-methyl-3- heptanone, 6-methyl-5-hepten-2-one, 3-oxo-2-pentyl-1-cyclopentaneacetate methyl, 1- (4-methylphenyl) -1-ethanone (4-methylacetophenone), 5-methyl-2- (propan-2-ylidene) cyclohexanone, 5-methyl-2- (prop-1-en-2-yl ) cyclohexanone, 2- methyl-5- (prop-1-en-2-yl) cyclohex-2-enone, 5-methyl-exo-tricycle [6.2.1.0 (2,7)] undecan-4-one, 3 -methyl-4- (1,2,2-trimethylpropyl) -4-penten-2-one, 2-naphthalenyl-1-ethanone, 1- (octahydro-2,3,8,8-tetramethylbenzene-2-naphthalenyl) -1- ethanone, 3,4,5,6,6-pentamethyl-3-hepten-2-one, 2-pentyl-1-cyclopentanone, 4-phenyl-2-butanone, 1-phenyl-1- ethanone, 2 - and 4-tert-butyl-1-cyclohexanone, 1- (4-tert-butylphenyl) -1-ethanone), 3,5,6,6-tetramethyl-4-methyleneheptan-2-one, 2,4,4 , 7-tetram ethyl-6-octen-3-one, 1,7,7-trimethyl-bicyclo [2.2.1] heptan-2-one, 2,6,6-trimethyl-1- cycloheptanone, 2,6,6-trimethyl- 2-cyclohexene-1,4-dione, 4- (2,6,6-trimethyl-2-cyclohexen-1-yl) -2-butanone, 1- (2,4,4-trimethyl-2-cyclohexen-1 -il) -2-buten-1-one, 1- (3,5,6-trimethyl-3-cyclohexen-1-yl) -1-ethanone, 2,2,5-trimethyl-5-pentyl-1- cyclopentanone and a C6-15 ketone of formula (R ') (R ") C> = O in which R' and R" are linear alkyl groups, b) optionally at least one repeat crosslinking unit of formula ** Formula ** in which all x are simultaneously either 0 or 1, and is 2, 3 or 4; R1 represents a C2-12 di-, tri- or tetra-hydrocarbon radical (depending on the value of y) optionally comprising 1 to 5 oxygen atoms; and R2 represents a hydrogen atom or a methyl group; alternatively, the repeat crosslinking unit is of formula ** Formula ** c) optionally at least one repeat unit of formulas ** Formula ** in which L is an oxygen atom or an NH group, B represents a group COOR4, a C6H5, a C6H4COOR4, an OR4, an R4COO, a CON (R4) 2, or a 2-oxopyrrolidin-l-yl or 2-oxoazepan-1-yl group and each R3 is a hydrogen atom or a group methyl, and each R4 represents a hydrogen atom, a C1-4 alkyl group or a group (C2H4O) qR3, where q is an integer ranging from 1 to 10; provided that at least 2% w / w of the complete repeating unit of formula (I) are units in which R is a group CH (R ') (R ") corresponding to a C6- aldehyde or ketone Perfument of formula (R ') (R ") C> = O.
priorityDate 2011-10-06-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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Total number of triples: 419.