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publicationDate 2015-04-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2532830-T3
titleOfInvention High discharge capacity electrolytic manganese dioxide and methods to produce it
abstract A method for producing electrolytic manganese dioxide (EMD) that has a high discharge capacity at high discharge rates by electrolysis in an electrolytic cell that has cathodic and anodic electrodes placed therein comprising the steps of: maintaining an aqueous electrolytic solution comprising sulfuric acid at a concentration of 20 to 60 grams of sulfuric acid per liter of solution, and manganese sulfate in the electrolytic cell at a temperature of 95 ° C to 98 ° C, solution having manganese sulfate therein in an amount sufficient to provide manganese ions in an amount of 5 to 50 grams of manganese ions per liter of solution; maintain the amount of sulfuric acid and manganese ions in the electrolyte solution at a ratio of sulfuric acid to manganese ions greater than or equal to 2; and applying electrical current to the electrodes to provide an anodic electrode current density of 26.9 to 64.5 amps / m2 (2.5 to 6 amp / ft2) and the high discharge capacity EMD produced is deposited in the anode electrode.
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