http://rdf.ncbi.nlm.nih.gov/pubchem/patent/ES-2444632-T3

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filingDate 2011-03-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
grantDate 2014-02-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_912af630a7f9d65edd9020f2cbcb3d71
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publicationDate 2014-02-26-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2444632-T3
titleOfInvention Thermoplastic moldable materials with improved optical properties
abstract Thermoplastic moldable materials, containing a mixture of (a) from 10 to 50% by weight, with respect to the sum of components (A), (B) and (C), of a methyl methacrylate polymer as component (A ), which can be obtained by polymerization of a mixture that is composed of (a1) from 90 to 100% by weight, with respect to (A), of methyl methacrylate as component (A1) and (a2) of 0 to 10% in weight, with respect to (A), of a C1-C8 alkyl ester of acrylic acid as a component (A2) and (b) of 20 to 60% by weight, with respect to the sum of components (A), (B) and (C), of a copolymer as a component (B), which can be obtained by polymerization of a mixture that is composed of (b1) from 70 to 90% by weight, with respect to (B), of a vinyl aromatic monomer as component ( B1) and (b2) from 10 to 30% by weight, with respect to (B), of a vinyl cyanide as component (B2) and (c) from 20 to 70% by weight, with respect to the sum of the components (A), (B) and (C ), of a graft copolymer as component (C), which can be obtained from (c1) from 50 to 70% by weight, with respect to (C), of a core as component (C1), which can be obtained by polymerization of a mixture of monomers that is composed of (c11) from 65 to 89.9% by weight, with respect to (C1), of a 1,3-diene as component (C11), and (c12) from 10 to 34, 9% by weight, with respect to (C1), of a vinyl aromatic monomer as a component (C12), and (c13) of 0.1 to 5% by weight, with respect to (C1), of a agglomeration polymer as a component (C13), and (c2) from 15 to 25% by weight, with respect to (C), of a first graft shell as component (C2), which can be obtained by polymerization of a mixture of monomers that is composed of ( c21) from 30 to 49.9% by weight, with respect to (C2), of a vinyl aromatic monomer as component (C21), and (c22) from 50 to 69.9% by weight, with respect to (C2), of a C1-C8 alkyl ester of methacrylic acid and / or a C1-C8 alkyl ester of acrylic acid as component (C22), and (c23) of 0.1 to 3% by weight, with respect to (C2), of a crosslinking monomer as component (C23), and (c3) of the 15 to 25% by weight, with respect to (C), of a second graft shell as component (C3), which can be obtained by polymerization of a mixture of monomers that is composed of (c31) from 20 to 80% by weight , with respect to (C3), of a C1-C8 alkyl ester of methacrylic acid as a component (C31) and (c32) of 20 to 80% by weight, with respect to (C3), of another monomer as component (C32), and (d) possibly customary additives as component (D) in amounts of up to 20% by weight, with respect to the sum of the components (A), (B) and (C), characterized in that - the component (C32) it is a vinylaromatic monomer and - the graft copolymer (C) is prepared by emulsion polymerization and is isolated from the reaction mixture by shear precipitation.
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