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grantDate 2013-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6aa9d08eef0db4f964da7753851448a5
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publicationDate 2013-01-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2394041-T3
titleOfInvention Process for the preparation of an alkanediol and a dialkyl carbonate
abstract Process for the preparation of an alkanediol and a dialkyl carbonate comprising: (a) reacting an alkylene carbonate and an alkanol feed in a first reaction zone under transesterification conditions to obtain a mixture of dialkyl carbonate products, alkanolsin convert, alkanediol, unconverted alkylene carbonate and dimers of alkanediol; (b) separate dialkyl carbonate and alkanol from the product mixture to obtain a tail product stream containing alkanediol, unconverted alkylene carbonate and dimers of alkanediol; (c) recover dialkyl carbonate; and (d) separating the alkanediol from the tail product stream to leave a recirculation stream comprising unconverted alkylene carbonate and dimers of the alkanediol, a process further comprising: (e) passing at least part of the recirculation stream to a second reaction zone in which the alkanediol dimers are converted to high boiling alkanediol oligomers, producing an oligomer containing oligomers; (f) separating the high boiling oligomers from the effluent containing the oligomers producing a remaining stream that contains alkylene carbonate; and (g) recycle the remaining stream containing alkylene carbonate to the first reaction zone.
priorityDate 2007-01-23-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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