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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_6c28a0091fbeaa7cd4bf0ef53e9a7597
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publicationDate 2012-03-16-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2376766-T3
titleOfInvention Polyester-polyacrylate dispersions with reactive diluents based on compounds containing lactone groups
abstract Process for the preparation of aqueous polyester-polyacrylate dispersions with an organic solvent content of 0 to 5% by weight in relation to the dispersion, characterized in that in a first step a polymerization (P) is prepared by polymerization A) of a mixture of vinyl monomers A1) to A4) suitable for radical copolymerization, containing components selected from the group of compounds: A1) esters of (meth) acrylic acid without OH groups, if necessary in admixture with vinyl aromatics, A2 ) hydroxy-functional vinyl monomers and / or hydroxy-functional (meth) acrylic acid esters, A3) ionic and / or potentially ionic monomers, suitable for radical polymerization as well as A4) other monomers, other than compounds of components A1) to A3 ), suitable for radical polymerization in the presence of B) at least one oligoester based on compounds containing lactone groups with a hydroxyl number of 145 mg KOH / g at 710 mg of KOH / g, an acid number of £ 0.5 mg of KOH / g and an average OH functionality of 2.5 to 5, and then in a second step a polyol ester or several polyesters are mixed with C) a hydroxyl number of 10 to 500 mg of KOH / g of substance and an acid number of> 0.5 to £ 30 mg of KOH / g of substance and the polymerization mixture thus obtained in a further step is dispersed in water before or after the addition of a neutralizing agent.
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