| abstract |
An adhesive, coating or film composition applied to a surface comprising a polymer formed from at least one substituted N acrylamide monomer, whose monomer comprises at least one phosphonic or phosphonic acid or the ester functional group, wherein the monomer N-substituted acrylamide is represented by at least one of Formulas (I), (II), (III) or (IV) wherein Q is at least one divalent bond radical selected from the group consisting of one or more alkylene C1-C18, C6-C12 arylene, and aralkylene; wherein the linking group is substituted or not substituted by one or more C1-C4 alkyl, C1-C4 haloalkyl, halogen, - P (O) (OR4) (OR5), - Q'-P (O) (OR4 ) (OR5), - P (O) (OR4) (R6), - Q'-P (O) (OR4) (R6), hydroxy or C1-C4 alkoxy; or Q is a C2-C12 alkylene interrupted by one or more - O -, - S -, - NR4 -, - O (CO) -, - S (CO) -, - OC (O) O -, - NR4 - C (O) - O -, - C (O) - or - NR4 (CO) -; R1 and R2 are independently hydrogen, branched or unbranched C1-C4 alkyl; R3 is hydrogen or C1-C4 alkyl, - Q "- P (O) (OR4) (OR5) or - Q" - P (O) (OR4) (R6); Q 'and Q "are the same or different and are at least one divalent radical selected from the group consisting of one or more of a C1-C18 alkylene, C6-C12 arylene, and aralkylene; wherein the linking group is substituted or is not substituted by one or more C1-C4 alkyl, C1-C4 haloalkyl, halogen, -P (O) (OR4) (OR5), -P (O) (OR4) (R6), hydroxy or C1-C4 alkoxy; or Q 'and Q "are a C2-C12 alkylene interrupted by one or more - O -, - S -, - NR4 -, - O (CO) -, S (CO) -, - OC (O) O -, - NR4 - C (O) - O -, - C (O) - or - NR4 (CO) -; R4 and R5 are independently H, C1-C4 alkyl wherein C1-C4 alkyl is branched or unbranched, substituted or unsubstituted by C1-C4 alkyl, C6-C12 aryl or halogen; and R6 is C1-C8 branched or unbranched alkyl, aryl, aralkyl, wherein C1-C8 alkyl, aryl, aralkyl is substituted or not substituted by one or more C1-C4 alkyl, C1-C4 haloalkyl or halogen, in where at least one of R4 or R5 of Formulas (I) or (III) is hydrogen, and where the surface is polar and is selected from the group consisting of particles of metallic pigment, metal, glass, ceramic fibers and sheets of metal. |