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filingDate 2001-04-04-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_2535a94beac85e949af4085bf9651579
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publicationDate 2004-10-01-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber ES-2187344-B1
titleOfInvention PROCEDURE FOR CONVERTING DIHYDROTAGETONE IN A COMPOUND WITH TWO CHIRAL CENTERS WITH COCONUT FLAVOR.
abstract Procedure to convert dihydrotagetone intona compound with two chiral centers with coconut flavor.n n n A natural acyclic monoterpene ketone andncheap (dihydrotagetone) of formula (4), isolated fromnTagetes sp. oil, oxidized evenly withnmeta-periodate / potassium permanganate producingnacidn2,6-dimethyl-4-oxo-heptanoicn of formula (3), the reduction of 3 with metal hydride, such asnsodium borohydride or lithium aluminum hydride provided then4-hydroxy acid of formula (2) that without isolationnunderwent lactonization in an acidic medium producingn5-isobutyl-3-methyl-4,5-dihydro-2 (3H) -furanonenwith two chiral centers of formula (1) as lactone analognof whiskeyn5-Butyl-4-methyl-4,5-dihydro-2 (3H) -furanonen of formula (1a) responsible for the high quality of beveragesnalcoholics (whiskey, wine, brandy and Scotch whiskey), in addition, then5-butyl-4-nmethyl-4,5-dihydro-2 (3H) -furanonen of formula (1a) with coconut flavor is also an analogue of aldehydenof coco γ-nonalactone, F.E.M.A. No. 2751) ofnformula (1b), which is responsible for the aromatization of a broadnseries of food products that include baked goods andnof pastry
priorityDate 2001-03-29-04:00^^<http://www.w3.org/2001/XMLSchema#date>
type http://data.epo.org/linked-data/def/patent/Publication

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