abstract |
The present disclosure relates to the production of polyacrylonitrile-based polymers with high conversion by a process comprising reacting acrylonitrile with at least one comonomer in the presence of a radical initiator in a liquid medium, wherein the radical initiator is present in an amount of from about 0.6 wt % to about 1.8 wt %, relative to the amount of acrylonitrile, and wherein no chain transfer agent is present, The polyacrylonitrile-based polymers produced may be used for producing carbon fiber, typically carbon fiber used in manufacturing composite materials. |