http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-3781582-A1
Outgoing Links
| Predicate | Object |
|---|---|
| assignee | http://rdf.ncbi.nlm.nih.gov/pubchem/patentassignee/MD5_fae58fdf2cd9c6fe6f3ce395064f3ddc |
| classificationCPCAdditional | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-65912 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-65908 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F210-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F2420-01 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F2420-06 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F2420-04 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F2410-01 |
| classificationCPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-65908 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F4-65912 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F210-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F210-18 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C08F210-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F17-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07F7-28 |
| classificationIPCInventive | http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F210-16 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-28 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F7-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C07F17-00 http://rdf.ncbi.nlm.nih.gov/pubchem/patentipc/C08F4-6592 |
| filingDate | 2019-04-15-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| inventor | http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_a4b6c096a36e87adfa5b94731e9cdfb0 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_9b27aa45c9d3614582e03759f4a9dd45 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_e5c39aacf1eee17679a7e5e27bb773b7 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_81213a050f5c0b37def81cd94238a4b7 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_880c65fb506604f396170d64bdd92326 http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_cf199345543fcc046e98558dd2a82d9e |
| publicationDate | 2021-02-24-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| publicationNumber | EP-3781582-A1 |
| titleOfInvention | Metal complex comprising amidine and indole fused cyclopentadienyl ligands |
| abstract | A metal complex of the formula (1) InCyLMZ p (1), wherein M is a group 4 metal Z is an anionic ligand, p is number of 1 to 2, preferably 2, InCy is an indole fused cyclopentadienyl-type ligand of the formula (2) wherein R 1 means for each index m individually a C 1 -C 4 -alkyl that substitutes a hydrogen atom of the benzene ring, m is a number of 0 to 4, preferably 0 to 2, in particular 0, R 2 means C 1 -C 10 -alkyl, C 5 - C 10 -cycloalkyl, and an unsubstituted or C 1 -C 10 -alkyl or C 1 -C 4 -dialkyl amino substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -20 alkyl substituted phenyl, more preferably methyl, phenyl or di-C 1 -C 4 -alkyl substituted phenyl, in particular di-tert.-butyl-phenyl, R 3 , R 4 and R 5 being individually selected from the group of hydrogen, C 1 -C 4 -alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aryl, in particular unsubstituted or C 1 -C 4 -alkyl substituted phenyl whereby preferably R 3 , R 4 and R 5 being individually selected from the group of hydrogen, C 1 -C 4 -alkyl, unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aryl, in particular C 1 -C 4 -alkyl substituted phenyl, more preferably at least one of the radicals R 3 to R 5 shall mean C 1 -C 4 -alkyl, in particular methyl, i-propyl and phenyl and, L is an amidinate ligand of the formula (3) (3) wherein the amidine-containing ligand is covalently bonded to the metal M via the imine nitrogen atom, and Sub 1 is an unsubstituted or C 1 -C 4 -alkyl and/or halogen, in particular chlorine or fluorine substituted C 6 -C 10 -aromatic substituent, in particular phenyl and Sub 2 is a substituent comprising a heteroatom of group 15, through which Sub 2 is bonded to the imine carbon atom or Sub 1 and Sub 2 together with the imino group they are connected to form a ligand of formula (3a) wherein the amidine-containing ligand (3a) is covalently bonded to the metal M via the imine nitrogen atom N 2 , wherein the benzo ring fused to the amidine ring may be unsubstituted or contain further substituents R 7 , which are individually of the index "q" selected from the group of hydrogen, C 1 -C 4 -alkyl and halogen and whereby q is a number of 0 to 4, preferably 0 to 2, most preferably 0, Sub 4 is an aliphatic or aromatic cyclic or linear substituent comprising a group 14 atom through which Sub4 is bonded to the amino nitrogen atom N 1, preferably Sub4 is a C 6 -C 10 -aromatic ring, preferably phenyl which is unsubstituted or substituted by one or more substituents from the group selected from halogen, in particular Cl or F and C 1 -C 4 -alkyl, preferably Sub4 is a 2,6-di-fluorophenyl. |
| priorityDate | 2018-04-16-04:00^^<http://www.w3.org/2001/XMLSchema#date> |
| type | http://data.epo.org/linked-data/def/patent/Publication |
Incoming Links
Total number of triples: 261.