http://rdf.ncbi.nlm.nih.gov/pubchem/patent/EP-3333158-A1

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classificationCPCInventive http://rdf.ncbi.nlm.nih.gov/pubchem/patentcpc/C07D307-24
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filingDate 2013-06-10-04:00^^<http://www.w3.org/2001/XMLSchema#date>
inventor http://rdf.ncbi.nlm.nih.gov/pubchem/patentinventor/MD5_04a5b979406e7c4107b6c0e06cd41d2d
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publicationDate 2018-06-13-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3333158-A1
titleOfInvention Method for producing purified dialkyl-furan-2,5-dicarboxylate by physical separation and solid liquid separation
abstract A process to produce a purified dimethyl-furan-2,5-dicarboxylate (DMFD) by feeding furan dicarboxylic acid and methanol to an esterification zone to generate, in the absence of an esterification catalyst, a crude diester composition, and purifying the crude diester composition with a physical separation process followed by crystallization, solid liquid separation, and optionally drying to produce a purified DMFD composition. A portion of the stream generated by solid liquid separation can be dissolved and subjected to crystallization and solid liquid separation repeatedly. The process is useful to produce a purified DMFD composition having a low b*, at least 98 wt.% DAFD solids, and a low concentration of 5-(methoxycarbonyl)furan-2-carboxylic acid (MCFC) and methyl 5-formylfuran-2-carboxylate (MFFC).
priorityDate 2012-06-22-04:00^^<http://www.w3.org/2001/XMLSchema#date>
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