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publicationDate 2018-02-21-04:00^^<http://www.w3.org/2001/XMLSchema#date>
publicationNumber EP-3284762-A1
titleOfInvention Fluoropolymers comprising tetrafluoroethene and one or more perfluorinated alkyl allyl ether comonomers
abstract A tetrafluoroethene copolymer having a melting point of from about 250 °C to about 326 °C, having a melt flow index (MFI at 372 °C and 5 kg load) of 0.5-50 grams / 10 minutes and having at least 89 % by weight of units derived from tetrafluoroethene and from about 0.5 to about 6 % by weight of units derived from at least one perfluorinated alkyl allyl ether (PAAE) comonomer and from 0 to 4 % by weight of units derived from one or more co-polymerizable optional comonomers, wherein the total amounts of units of the polymer gives 100 % by weight and wherein the at least one PAAE corresponds to the general formula: n€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ CF 2 =CF-CF 2 -O-Rf€ƒ€ƒ€ƒ€ƒ€ƒ(I) nwhere Rf is a perfluorinated alkyl group having from 1 to 10 carbon atoms. Also provided are methods of making the polymer, and articles comprising the polymer and methods of making the articles.
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